AMASHIDI EDATHA YOKUPHEPHA

Ngokusho kwe-UN GHS ukubuyekeza 8

Inguqulo: 1.0

Usuku Lokudala: Julayi 15, 2019

Idethi Yokubuyekeza: Julayi 15, 2019

ISIQEPHU 1: Ukuhlonza

1.1Isihlonzi somkhiqizo weGHS

1.2Ezinye izindlela zokuhlonza

1.3 Ukusetshenziswa okunconyiwe kwamakhemikhali kanye nemikhawulo ekusetshenzisweni

1.4Imininingwane yomphakeli

1.5Inombolo yocingo yesimo esiphuthumayo

ISIQEPHU 2: Ukuhlonzwa kwengozi

2.1 Ukuhlukaniswa kwento noma ingxube

Uketshezi oluvuthayo, Isigaba 1

Ubuthi obunamandla - Isigaba 3, Oral

Ubuthi obunamandla - Isigaba 3, Dermal

Ukucasuka kwesikhumba, Isigaba 2

Ukucasuka kwamehlo, Isigaba 2

Ubuthi obunamandla - Isigaba 2, Ukuhogela

Ubuthi obukhethekile besitho esiqondiwe - ukuchayeka okukodwa, Isigaba 3

Iyingozi endaweni yasemanzini, yesikhashana (Acute) – Isigaba Esibucayi 1

Iyingozi endaweni yasemanzini, yesikhathi eside (Ehlala njalo) – Isigaba Esingamahlalakhona 1

2.2Izakhi zelebula zeGHS, ezifaka izitatimende zokuqapha

2.3Ezinye izingozi ezingabangeli ukuhlukaniswa

ayikho idatha etholakalayo

ISIQEPHU 3: Ukwakhiwa/ulwazi ngezithako

3.1Izinto

ISIQEPHU 4: Izinyathelo zosizo lokuqala

4.1Incazelo yezinyathelo zosizo lokuqala ezidingekayo

Uma ehogelwe

Umoya omusha, phumula. Isikhundla esiqondile. Bheka ukuze uthole usizo lwezempilo.

Ukulandela ukuthintana kwesikhumba

Susa izingubo ezingcolile. Hlanza isikhumba ngamanzi amaningi noma ishawa. Bheka ukuze uthole usizo lwezempilo .

Ukulandela ukuthintana kwamehlo

Hlanza ngamanzi amaningi imizuzu embalwa (susa amalensi okuxhumana uma kungenzeka kalula). Bheka ngokushesha ukuze uthole usizo lwezempilo.

Ukulandela ukungeniswa

Hlanza umlomo. UNGABANZI ukuhlanza. Nikeza ingilazi eyodwa noma ezimbili zamanzi okuphuza. Bheka ukuze uthole usizo lwezempilo .

4.2Izimpawu/imiphumela ebaluleke kakhulu, ebucayi futhi ebambezelekile

Ingcaphuno evela ku-ERG Guide 131 [Uketshezi Oluvuthayo - Olunobuthi]: BUBUTHI; ingase ibulale uma ihogelwa, imuncwa noma imuncwe ngesikhumba. Ukuhogela umoya noma ukuthintana nezinye zalezi zinto kuzocasula noma kushise isikhumba namehlo. Umlilo uzokhipha amagesi acasulayo, abolayo kanye/noma anobuthi. Umhwamuko ungabangela isiyezi noma ukufutha. Ukugeleza kwamanzi okulawula umlilo noma amanzi ahlanjululwayo kungase kubangele ukungcola. (ERG, 2016)

4.3 Inkomba yokunakekelwa ngokushesha kanye nokwelashwa okukhethekile okudingekayo, uma kunesidingo

Usizo lokuqala olusheshayo: Qinisekisa ukuthi ukususwa kokungcola okwanele kwenziwe. Uma isiguli singaphefumuli, qala ukuphefumula okwenziwayo, okungcono kakhulu nge-resuscitator-valve, idivayisi ye-bag-valve-mask, noma imaski yephakethe, njengoba uqeqeshiwe. Yenza i-CPR njengoba kudingeka. Hlanza ngokushesha amehlo angcolile ngamanzi ageleza kancane. Ungabangeli ukuhlanza. Uma kwenzeka ukuhlanza, ncika isiguli phambili noma ubeke ohlangothini lwesobunxele (indawo yekhanda elibheke phansi, uma kungenzeka) ukuze ugcine umoya ovulekile futhi uvimbele ukulangazelela. Gcina isiguli sithule futhi ugcine izinga lokushisa lomzimba elivamile. Thola usizo lwezempilo. Ama-ketones kanye nama-compounds ahlobene

ISIQEPHU 5: Izinyathelo zokucisha umlilo

5.1Imidiya yokucisha efanelekile

Uma impahla ivutha noma ibandakanyeka emlilweni: Ungawucishi umlilo ngaphandle uma ukugeleza kungavinjwa. Cisha umlilo usebenzisa i-ejenti efanele uhlobo lomlilo ozungezile. (Impahla ngokwayo ayishi noma ishe kanzima.) Pholisa zonke izitsha ezithintekile ngamanzi aphuphumayo. Gcoba amanzi ukusuka kude ngangokunokwenzeka. Sebenzisa igwebu, ikhemikhali eyomile, noma i-carbon dioxide. Gcina amanzi aphumayo ngaphandle kwendle nemithombo yamanzi. I-Chloroacetone, izinzile

5.2 Izingozi ezithile ezivela ekhemikhali

Ingcaphuno evela ku-ERG Guide 131 [Izinto Eziwuketshezi Ezivuthayo - Ezinobuthi]: ZIVUSE KAKHULU: Zizovutha kalula ngenxa yokushisa, izinhlansi noma amalangabi. Imihwamuko ingase yakhe izingxube eziqhumayo ngomoya. Izihwamuko zingahamba ziye emthonjeni wokuthungela bese zibuyela emuva. Imihwamuko eminingi isindayo kunomoya. Zizosakazeka emhlabathini futhi ziqoqe ezindaweni eziphansi noma ezivaliwe (indle, izindlu zangaphansi, amathangi). Ukuqhuma komhwamuko nobungozi bobuthi endlini, ngaphandle noma ezindleleni zendle. Lezo zinto eziklanywe nge-(P) zingase zenze i-polymerly ngokuqhuma lapho kushisa noma zibandakanyiwe emlilweni. Ukugeleza kwendle kungadala ingozi yomlilo noma yokuqhuma. Iziqukathi zingaqhuma uma zishisiwe. Uketshezi oluningi lulula kunamanzi. (ERG, 2016)

5.3Izenzo zokuvikela ezikhethekile zabacimi bomlilo

Sebenzisa isifutho samanzi, impushana, igwebu elimelana notshwala, isikhutha. Uma kuba nomlilo: gcina izigubhu, njll., zipholile ngokufafaza ngamanzi.

ISIGABA 6: Izinyathelo zokudedelwa ngengozi

6.1Izinyathelo zokuzivikela, izinto zokuzivikela kanye nezinqubo eziphuthumayo

Susa yonke imithombo yokuthungela. Phuma endaweni eyingozi! Xhumana nochwepheshe! Isivikelo somuntu siqu: isihlungi sokuphefumula samagesi aphilayo kanye nezihwamuko ezivumelaniswe nokuhlangana komoya kwento. Ukungenisa umoya. Qoqa uketshezi oluvuzayo ezitsheni ezimboziwe. Munca uketshezi olusele esihlabathini noma ekumunceni okungenayo. Bese ugcina bese ulahla ngokwemithetho yendawo.

6.2 Izinyathelo zokuphepha kwemvelo

Susa yonke imithombo yokuthungela. Phuma endaweni eyingozi! Xhumana nochwepheshe! Isivikelo somuntu siqu: isihlungi sokuphefumula samagesi aphilayo kanye nezihwamuko ezivumelaniswe nokuhlangana komoya kwento. Ukungenisa umoya. Qoqa uketshezi oluvuzayo ezitsheni ezimboziwe. Munca uketshezi olusele esihlabathini noma ekumunceni okungenayo. Bese ugcina bese ulahla ngokwemithetho yendawo.

6.3 Izindlela nezinto zokuvikela kanye nokuhlanza

Ukucatshangelwa kwemvelo - ukuchitheka komhlaba: Yimba umgodi, ichibi, ichibi, indawo yokubamba ukuze iqukathe uketshezi noma okuqinile. /SRP: Uma isikhathi sivuma, imigodi, amachibi, amachweba, imigodi yokucwiliswa emanzini, noma izindawo zokubamba kufanele zivalwe ngomugqa we-membrane oguquguqukayo ongenakunyakaziswa./ Ukugeleza kwe-Dike surface kusetshenziswa inhlabathi, izikhwama zesihlabathi, i-polyurethane enegwebu, noma ukhonkolo onegwebu. Mumba uketshezi oluyinqwaba ngomlotha wempukane, impushana kasimende, noma ama-sorbent entengiso. I-Chloroacetone, izinzile

ISIQEPHU 7: Ukuphatha nokugcina

7.1 Izinyathelo zokuphepha zokuphatha ngendlela ephephile

AKUKHO amalangabi avulekile, AKUKHO izinhlansi kanye AKUKHO nokubhema. Ngaphezu kuka-35°C zisebenzisa isistimu evaliwe, umoya omncane kanye nezinto zikagesi ezingaqhumi. Ukuphatha endaweni enomoya omuhle. Gqoka izingubo ezifanele zokuzivikela. Gwema ukuthinta isikhumba namehlo. Gwema ukwakheka kothuli nama-aerosol. Sebenzisa amathuluzi angashiyi izinhlansi. Vimbela umlilo obangelwa umusi wokukhipha i-electrostatic.

7.2Imibandela yokugcina ephephile, kuhlanganise nanoma yikuphi ukungahambisani

Gcina kuphela uma uzinzile. Ingashi. Ihlukaniswe nama-oxidants aqinile nokudla nezinto eziphakelayo. Gcina kumnyama.Gcina kuphela uma uzinzile. Ingashi. Ihlukaniswe nama-oxidants aqinile, ukudla nokudla. Gcina kumnyama … Ngaphezulu kuka-35 deg C sebenzisa isistimu evaliwe, umoya omncane, kanye nezinto zikagesi ezingaqhumi.

ISIGABA 8: Izilawuli zokuchayeka/ukuvikelwa komuntu siqu

8.1Lawula amapharamitha

Amanani omkhawulo Wokuchayeka Emsebenzini

I-TLV: 1 ppm njenge-STEL; (isikhumba)

Amanani omkhawulo webhayoloji

ayikho idatha etholakalayo

8.2 Izilawuli zobunjiniyela ezifanele

Qinisekisa ukuthi kungena umoya owanele. Bamba ngokuhambisana nenhlanzeko enhle yezimboni kanye nokuphepha. Setha izindawo zokuphuma eziphuthumayo kanye nendawo yokuqeda ubungozi.

8.3 Izinyathelo zokuvikela umuntu ngamunye, njengempahla yokuzivikela yomuntu siqu (PPE)

Ukuvikela iso/ubuso

Gqoka isivikelo sobuso noma isivikelo samehlo ngokuhambisana nokuvikela ukuphefumula.

Ukuvikelwa kwesikhumba

Amagilavu ​​okuzivikela. Izingubo zokuzivikela.

Ukuvikelwa kokuphefumula

Sebenzisa umoya omncane, umoya okhipha umoya wendawo noma ukuvikela ukuphefumula.

Izingozi ezishisayo

ayikho idatha etholakalayo

ISIQEPHU 9: Izakhiwo zomzimba kanye namakhemikhali kanye nezici zokuphepha

ISIQEPHU SE-10: Ukuzinza nokusebenza kabusha

10.1 Ukwenza kabusha

Umuthi upholisa kancane ngaphansi kwethonya lokukhanya. Lokhu kudala ingozi yomlilo noma yokuqhuma. Ibola lapho ishisa nalapho isha.

10.2Ukuzinza kwamakhemikhali

Ijika ibe mnyama bese ishintshashintsha ekuchazweni isikhathi eside ekukhanyeni, ingase iqiniswe ngamanzi angu-0.1% noma u-1.0% we-calcium carbonate.

10.3 Amathuba okusabela okuyingozi

Ivutha uma ichayeke ekushiseni noma elangabini, noma izikhuthazi mshini.I-CHLOROACETONE iba mnyama futhi ishintshe ukuchayeka ekukhanyeni isikhathi eside [Merck]. Lokhu kwenzeka ebhodleleni ngesikhathi sokugcinwa iminyaka emibili eshalofini ekukhanyeni okuhlukanisiwe. Ngemva kwezinsuku ezimbalwa ibhodlela lisusiwe, laqhuma [Ind. Eng. Izindaba 9: 184(1931)]. Izinziswa ngokwengeza amanzi angu-0.1% noma i-0.1% CaCO3.

10.4Izimo okufanele uzigweme

ayikho idatha etholakalayo

10.5Izinto ezingahambelani

UMLANDO WEKHEMIKHALI: Ukuzisebenza ngokwakho. I-Chloroacetone yayiphenduke yaba mnyama ngesikhathi sokugcinwa kwayo iminyaka emibili ngokwayo ekukhanyeni okuhlukanisiwe. Ezinsukwini ezimbalwa ngemva kokususwa kwebhodlela le-chloroacetone, laqhuma. I-chloroacetone yenziwe i-polymer yaba into emnyama efana ne-Ind. Eng. Izindaba 9: 184(1931). (REACTIVITY, 1999)

10.6Imikhiqizo yokubola eyingozi

Uma ishiselwa ukuze ibole ikhipha intuthu enobuthi obukhulu.

ISIGABA 11: Ulwazi lwe-toxicology

Ubuthi obunamandla

• Oral: LD50 Rat ngomlomo 100 mg/kg
• Ukuhogela: LC50 Igundane ukuhogela 262 ppm/1 ihora
• Dermal: ayikho idatha etholakalayo

Ukugqwala/ukucasuka kwesikhumba

ayikho idatha etholakalayo

Ukulimala okukhulu kwamehlo/ukucasuka

ayikho idatha etholakalayo

Ukuphefumula noma ukuzwela kwesikhumba

ayikho idatha etholakalayo

I-Gem cell mutagenicity

ayikho idatha etholakalayo

I-Carcinogenicity

ayikho idatha etholakalayo

Ubuthi bokuzala

ayikho idatha etholakalayo

STOT-ukuchayeka okukodwa

I-Lachrymation. Lo muthi uyacasula kakhulu amehlo, isikhumba kanye nendlela yokuphefumula.

Ukuchayeka okuphindaphindiwe kwe-STOT

ayikho idatha etholakalayo

Ingozi yokuphefumula

Ukungcoliswa komoya okuyingozi kungafinyelelwa ngokushesha kakhulu ekuhwamukeni kwale nto kuma-20°C.

ISIQEPHU 12: Ulwazi lwemvelo

12.1 Ubuthi

• Ubuthi ezinhlanzini: ayikho idatha etholakalayo
• Ubuthi ku-daphnia nezinye izilwane ezingenamgogodla zasemanzini: akukho datha etholakalayo
• Ubuthi ku-algae: ayikho idatha etholakalayo
• Ubuthi kuma-microorganisms: ayikho idatha etholakalayo

12.2 Ukuphikelela kanye nokwehliswa kwesithunzi

ayikho idatha etholakalayo

12.3 Amandla e-Bioaccumulative

Isilinganiso se-BCF soku-3 sibalwa ezinhlanzini ze-1-chloro-2-propanone(SRC), kusetshenziswa i-log ye-Kow elinganiselwe engu-0.02(1) kanye nesibalo esisuselwa ekuhlehleni (2). Ngokohlelo lokuhlukanisa (3), le BCF iphakamisa ukuthi amandla okugxilwa kwezinto eziphilayo emanzini aphansi (SRC).

12.4Ukuhamba emhlabathini

Kusetshenziswa indlela yokulinganisa yesakhiwo esekelwe kuzinkomba zokuxhunywa kwamangqamuzana(1), i-Koc ye-1-chloro-2-propanone ingalinganiselwa ku-5(SRC). Ngokohlelo lokuhlukanisa(2), leli nani elilinganiselwe le-Koc liphakamisa ukuthi i-1-chloro-2-propanone kulindeleke ukuthi ibe nokuhamba okuphezulu kakhulu enhlabathini.

12.5Eminye imiphumela emibi

ayikho idatha etholakalayo

ISIQEPHU 13: Ukucatshangelwa kokulahlwa

13.1 Izindlela zokulahla

Umkhiqizo

Izinto ezisetshenziswayo zingalahlwa ngokuyiswa endaweni enelayisensi yokucekela phansi amakhemikhali noma ngokushiswa okulawulwayo ngokukhuhla igesi ewuketshezi. Ungangcolisi amanzi, ukudla, ukudla noma imbewu ngokuwagcina noma ukulahla. Ungachithi kumasistimu endle.

Iphakheji engcolile

Iziqukathi zingahlanzwa kathathu (noma okulinganayo) futhi zinikezwe ukuze zigaywe kabusha noma zilungiswe kabusha. Kungenjalo, iphakethe lingabhobozwa ukuze lingasebenziseki kwezinye izinjongo bese lilahlwa endaweni yokulahla imfucumfucu ehlanzekile. Ukushiswa okulawulwayo nge-flue gas scrubbing kuyenzeka ezintweni zokupakisha ezivuthayo.

ISIQEPHU 14: Ulwazi lwezokuthutha

14.1 Inombolo ye-UN

14.2Igama le-UN Elifanelekile Lokuthumela

14.3Izigaba zengozi yezokuthutha

14.4Iqembu lokupakisha, uma likhona

14.5Izingozi zemvelo

14.6 Izinyathelo ezikhethekile zokuqapha umsebenzisi

ayikho idatha etholakalayo

14.7Ezokuthutha ngobuningi ngokuya ngamathuluzi e-IMO

ayikho idatha etholakalayo

ISIGABA 15: Ulwazi lokulawula

15.1Imithetho yokuphepha, yezempilo kanye neyemvelo eqondene ngqo nomkhiqizo okukhulunywa ngawo

ISIQEPHU 16: Olunye ulwazi

Ulwazi ngokubuyekezwa

Izifinyezo kanye nama-akhronimi

• I-CAS: Isevisi ye-Chemical Abstracts
• I-ADR: Isivumelwano SaseYurophu esiphathelene nokuthwala Kwamazwe Ngamazwe Kwempahla Eyingozi Ngomgwaqo
• I-RID: Umthetho ophathelene nokuthuthwa kwamazwe ngamazwe kwezimpahla eziyingozi ngololiwe
• I-IMDG: Impahla Eyingozi Yasolwandle Yamazwe Ngamazwe
• I-IATA: Inhlangano Yezokuthutha Ngezindiza Yamazwe Ngamazwe
• I-TWA: Isikhathi Esinesisindo Esimaphakathi
• STEL: Umkhawulo wokuchayeka wesikhathi esifushane
• I-LC50: I-Lethal Concentration 50%
• I-LD50: I-Lethal Dose 50%
• I-EC50: Ukugxila Okuphumelelayo 50%
• IPCS – I-International Chemical Safety Cards (ICSC), iwebhusayithi: http://www.ilo.org/dyn/icsc/showcard.home
• I-HSDB – Ibhange Ledatha Yezinto Eziyingozi, iwebhusayithi: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
• I-IARC – Isikhungo Samazwe Ngamazwe Sokucwaninga Ngomdlavuza, iwebhusayithi: http://www.iarc.fr/
• I-eChemPortal – I-Global Portal to Information on Chemical Substances yi-OECD, iwebhusayithi: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
• I-CAMEO Chemicals, iwebhusayithi: http://cameochemicals.noaa.gov/search/simple
• I-ChemIDplus, iwebhusayithi: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
• I-ERG – Incwadi Yomhlahlandlela Wezimpendulo Eziphuthumayo yoMnyango Wezokuthutha wase-US, iwebhusayithi: http://www.phmsa.dot.gov/hazmat/library/erg
• Isizindalwazi saseJalimane se-GESTIS sezinto eziyingozi, iwebhusayithi: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• I-ECHA - I-European Chemicals Agency, iwebhusayithi: https://echa.europa.eu/

Izithenjwa

Olunye Ulwazi

Ngemva kokuthintana nokwakheka kwamabhamuza awuketshezi kungase kubambezeleke kuze kudlule amahora ambalwa. Imikhawulo yeziqhumane akwaziwa ezincwadini, nakuba into iyakwazi ukuvutha futhi ine-flash point engaphansi kuka-61°C. Inani lomkhawulo wokuchayeka emsebenzini akufanele lidlule nganoma iyiphi ingxenye ukuchayeka okusebenzayo.Isexwayiso sephunga lapho ivelu yomkhawulo wokuchayeka yeqiwe asanele.Isinzinzisi esingeziwe noma isivimbeli singaba nomthelela ezintweni ezinobuthi zale nto; thintana nochwepheshe.

Noma yimiphi imibuzo mayelana nale SDS, Sicela uthumele umbuzo wakho kuinfo@mit-ivy.com